Title of article
Organocatalytic Michael addition of indanone carboxylates to vinyl selenone for the asymmetric synthesis of polycyclic pyrrolidines
Author/Authors
Silvia Sternativo، نويسنده , , Ola Walczak، نويسنده , , Benedetta Battistelli، نويسنده , , Lorenzo Testaferri، نويسنده , , Francesca Marini، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
10536
To page
10541
Abstract
A Michael addition of racemic indanone carboxylates to vinyl selenone catalyzed by C6′hydroxyl cinchona derivatives is the key step of a synthetic sequence for a practical access to highly enantioenriched (up to 98% ee) polycyclic pyrrolidines bearing contiguous tertiary and quaternary stereocenters.
Keywords
Selenium , Organocatalysis , Asymmetric synthesis , Pyrrolidines , aminoesters
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1105246
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