• Title of article

    One-pot synthesis of unsymmetrical benzils and N-heteroarenes through nucleophilic aroylation catalyzed by N-heterocyclic carbene

  • Author/Authors

    Yumiko Suzuki، نويسنده , , Mai Murofushi، نويسنده , , Kei Manabe، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2013
  • Pages
    4
  • From page
    470
  • To page
    473
  • Abstract
    An efficient one-pot synthesis of various unsymmetrical benzils via N-heterocyclic carbene (NHC)-catalyzed aroylation of N-phenylimidoyl chlorides with aromatic aldehydes followed by acidic hydrolysis has been developed. The one-pot procedure was extended to synthesis of quinoxalines and pyrazines by condensation/annulation of unsymmetrical benzils generated in situ with diamines.
  • Keywords
    Quinoxaline , Pyrazine , Unsymmetrical benzil , One-pot synthesis , N-heterocyclic carbene
  • Journal title
    Tetrahedron
  • Serial Year
    2013
  • Journal title
    Tetrahedron
  • Record number

    1105326