Title of article :
Syntheses of 6-8-5 tricyclic ring systems by carbonylative [2+2+1] cycloaddition of bis(allene)s
Author/Authors :
M.T. Soraya Shafawati، نويسنده , , Akira Matsuda and Fuyuhiko Inagaki، نويسنده , , Takamasa Kawamura، نويسنده , , Chisato Mukai، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
The synthetic route for the construction of the 6-8-5 tricyclic carbon frameworks has been developed. The [RhCl(CO)dppp]2-catalyzed intramolecular Pauson–Khand-type reaction of the bis(allene)s, derived from dimedone, provided the corresponding bicyclo[6.3.0] skeleton in one operation.
Keywords :
Bis(allene)s , Rhodium , Medium-sized ring formation
Journal title :
Tetrahedron
Journal title :
Tetrahedron