Title of article
Titanocene-promoted stereoselective eliminations on epoxy alcohols derived from R-(−)-carvone
Author/Authors
A. Fern?ndez-Mateos، نويسنده , , P. Herrero Teij?n، نويسنده , , R. Rubio Gonz?lez، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
6
From page
1611
To page
1616
Abstract
The reaction of several stereoisomeric epoxy alcohols, obtained from R-(−)-carvone, and their corresponding formates, acetates, and benzoates, promoted by Cp2TiCl has been studied. The different outcomes of the reaction of epoxy derivatives are rationalized in terms of mechanistically biased processes. The radicals emerging from oxirane cleavage provide two types of reaction: dehydroxylation (deoxycarbonylation) and dehydrogenation.
Keywords
Radical reactions , Alcohols , Titanium , Elimination , Esters
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105470
Link To Document