Title of article
Facile access to novel chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes via tandem nucleophilic substitution and [4+2] hetero Diels–Alder reaction: experimental and theoretical study
Author/Authors
Satyanarayana Reddy Jaggavarapu، نويسنده , , Anand Solomon Kamalakaran، نويسنده , , Gaddamanugu Gayatri، نويسنده , , Matsyendranath Shukla، نويسنده , , Kavita Dorai، نويسنده , , Gopikrishna Gaddamanugu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
8
From page
2142
To page
2149
Abstract
An efficient synthesis of novel chromeno-2,6,9-trioxabicyclo-[3.3.1]nonadienes (CTOBN) scaffolds was achieved by mild base mediated reaction of 4-chloro-3-formylcoumarin and o-hydroxyacetophenones. The structure of the product was confirmed by X-ray analysis and the proposed mechanism was validated computationally at B3LYP/6-31G(d) level.
Keywords
Chromeno-2 , DFT , 4-Chloro-3-formylcoumarin , o-Hydroxyacetophenones , Tandem , 6
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105540
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