Title of article
Dipyrrolidinomethylaminophosphoric acid triamide (DPMPA) as an activator for the samarium diiodide-mediated reduction of alkyl and aryl halides
Author/Authors
Chriss E. McDonald، نويسنده , , Jeremy R. Ramsey، نويسنده , , David G. Sampsell، نويسنده , , Laura A. Anderson، نويسنده , , Jordan E. Krebs، نويسنده , , Samantha N. Smith، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
7
From page
2947
To page
2953
Abstract
The use of the conjugate base of dipyrrolidinomethylaminophosphoric triamide (DPMPA−) as an activator of samarium diiodide is reported. This phosphoramidate has been shown to be a very potent ligand, allowing for the efficient, low-temperature reduction of alkyl and aryl chlorides. Reductive cyclizations of haloalkenylnaphthalenes are also reported.
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105631
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