• Title of article

    Na2S2O4-Promoted Radical Addition Reaction of Perfluoroalkyl Iodides with Allenes and the TPd(0) -Catalyzed Stereoselective Sonogashira Coupling

  • Author/Authors

    Ma، Shengming نويسنده , , Alcohol، eaction of Addition Products with TPropargyl نويسنده , , Ma، Zhichao نويسنده ,

  • Pages
    -1262
  • From page
    1263
  • To page
    0
  • Abstract
    A Na2S2O4-promoted radical addition reaction of per­fluoroalkyl iodides with allenes affording 1-perfluoroalkyl-2-alken-2-yl iodides 3 in 52-69% yields has been developed. Kinetic re­solution of the Z\E mixture via the Pd(0)-catalyzed Sonogashira coupling reaction was applied to prepare pure vinylic iodides (Z)-3 and the related coupling products (E)-4 up to 98:2 E\Z ratio
  • Keywords
    cascade reactions , pyrrolizidines , indolizidines , quinolizidines
  • Journal title
    Astroparticle Physics
  • Record number

    110575

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=110575