Title of article
An efficient procedure for the synthesis of 2,3-unsaturated-O-glycosides: TiCl3(OTf) as the catalyst for type I Ferrier rearrangement
Author/Authors
Peiran Chen، نويسنده , , Lei Lin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
8
From page
4524
To page
4531
Abstract
An efficient type I Ferrier rearrangement reaction system for the synthesis of 2,3-unsaturated-O-glycosides has been established by using TiCl3(OTf) as the catalyst. A series of 2,3-unsaturated-O-glucosides were prepared from 3,4,6-tri-O-acetyl-d-glucal in good yield and high anomeric selectivity.
Keywords
2 , 3-Unsaturated-O-glycoside , 4 , Tri-O-acetyl-d-glucal , Type I Ferrier Rearrangement , 6-Tri-O-acetyl-d-glucal , TiCl3(OTf) , 3
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105816
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