Title of article :
4,4,6-Trimethyl-2-vinyl-1,3,2-dioxaborinane: An Efficient and Selective 2-Carbon Building Block for Vinylboronate Suzuki-Miyaura Coupling Reactions
Author/Authors :
Whiting، Andrew نويسنده , , Lightfoot، Andrew P. نويسنده , , Twiddle، Steven J. R. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
An extremely simple and efficient palladium-catalyzed coupling procedure for the synthesis of functionalized styrenes and dienes is utilized to demonstrate how 4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane can be employed to selectively undergo Suzuki-Miyaura coupling with a range of halide substrates.
Keywords :
Suzuki-Miyaura coupling , palladium(0) , vinylboronate ester , chemoselectivity
