Title of article
First total synthesis of natural pulsatilla saponin D via highly stereospecific glycosylation
Author/Authors
Minkyu Kim، نويسنده , , Eunyoung Lim، نويسنده , , Mankil Jung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
6
From page
5481
To page
5486
Abstract
The first total synthesis of pulsatilla saponin D, a potent anti-lung cancer natural product was accomplished in eight steps from l-arabinopyranoside in high overall yield via a highly stereospecific glycosylation featuring an oxocarbenium mechanism between the trisaccharide derivative and aglycone as the key step.
Keywords
Hederagenin , Stereospecific glycosylation , Pulsatilla saponin D , Total synthesis , Trisaccharide
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105931
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