Title of article
Highly efficient asymmetric-axle-supported N–O amides in enantioselective hydrosilylation of ketimines with trichlorosilane
Author/Authors
Wei Pan، نويسنده , , Yu Deng، نويسنده , , Jiang-Bo He، نويسنده , , Bing Bai، نويسنده , , Hua-Jie Zhu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
5
From page
7253
To page
7257
Abstract
A novel asymmetric-axle-supported chiral N–O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical −20 °C. High conversion yield and high enantioselectivity up to 96% were observed.
Keywords
Asymmetric-axle-supported , Hydrosilylation , ketimines , Trichlorosilane
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1106139
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