Title of article
Selective reactivity of electron-rich aryl iodides in the Heck arylation of disubstituted alkenes catalyzed by palladium–arylurea complexes
Author/Authors
Matthew R. Smith، نويسنده , , Young Jin Jang، نويسنده , , Jung Yun Kim، نويسنده , , Marco A. Ciufolini، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
13
From page
10139
To page
10151
Abstract
A catalyst consisting of 1 mol % of the 1:2 complex of Pd(OAc)2 with N-(4-carbethoxyphenyl)urea promotes the Heck arylation of 2- or 3-substituted, conjugated esters, nitriles, aldehydes, and ketones (an uncharacteristically broad range of substrates), but only with electron-rich aryl iodides (an uncharacteristically narrow range of halides).
Keywords
arylation , Arylureas , Palladium , Ligands , Heck reaction
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1106484
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