Title of article
Room temperature Fe(NO3)3·9H2O/TEMPO/NaCl-catalyzed aerobic oxidation of homopropargylic alcohols
Author/Authors
Jinxian Liu، نويسنده , , Shengming Ma، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
7
From page
10161
To page
10167
Abstract
A practical and eco-friendly aerobic oxidation of homopropargylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts at room temperature under atmospheric pressure was developed affording corresponding homopropargylic ketones with moderate to good yields. Aryl, heteroaryl as well as alkyl 1,2-allenic ketones were obtained by the isomerization of corresponding terminal homopropargylic ketones through column chromatographic workup on silica gel.
Keywords
aerobic oxidation , Iron nitrate , TEMPO , NaCl , Homopropargylic alcohol
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1106486
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