Title of article :
Tandem rearrangements of a cyclic bis-allene
Author/Authors :
Hussein H. Mustafa، نويسنده , , Mark S. Baird، نويسنده , , Jumaʹa R. Al Dulayymi، نويسنده , , Viacheslav V. Tverezovskiy، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions.
Keywords :
Cyclopropylidene , Sigmatropic shift , Allene , Ene-reaction
Journal title :
Tetrahedron
Journal title :
Tetrahedron