Title of article :
A Divergent Synthesis of Uncommon Sugars from Furanaldehyde
Author/Authors :
Wang، Peng George نويسنده , , Zhu، Lizhi نويسنده , , Talukdar، Arindam نويسنده , , Zhang، Guisheng نويسنده , , Kedenburg، James P. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A practical synthetic strategy has been developed for producing uncommon sugars. This method employed kinetic enzymatic resolution of 1-(2furyl)ethanol, and followed by NBS-mediated Achmatowicz rearrangement to construct (alpha),(beta)-unsaturated lactones. After further derivatization, five representative uncommon sugar units were successfully synthesized.
Keywords :
Achmatowicz rearrangement , enzymatic kinetic resolution , 1-(2-furyl)ethanol , uncommon sugar
