Title of article
Enantioselective Hydroxyvinylation with Lithioethenes
Author/Authors
Yuan، Yi نويسنده , , Harrison-Marchand، Anne نويسنده , , Maddaluno، Jacques نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1554
From page
1555
To page
0
Abstract
The enantioselective addition of lithioethenes to aldehydes was studied. Such asymmetric approach of the hydroxyvinylation is reported for the first time with promising ee, (up to 70% at -78 °C in THF), using mixed aggregates of the vinyllithium species and a chiral lithium amide.
Keywords
chiral lithium amide , asymmetric vinylation , mixed aggregates vinyllithiums
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110687
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