Title of article :
Phosphomolybdic Acid Supported on Silica Gel: An Efficient, Mild and Reusable Catalyst for the Chemoselective Hydrolysis of Acetonides
Author/Authors :
Yadav، J. S. نويسنده , , Raghavendra، S. نويسنده , , Satyanarayana، M. نويسنده , , Balanarsaiah، E. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Carbohydrate acetonides were chemoselectively cleaved to the corresponding diols by using environmentally benign phosphomolybdic acid (H3PMo12O40) supported on silica gel (PMASiC)2) at ambient temperature in a short span of 5-7 minutes in acetonitrile. Acid-labile protective groups such as THP, TBS, TBDPS, MOM, OMe and PMB were found to be stable under the reaction conditions.
Keywords :
acetonides , phosphomolybdic acid , chemoselective hydrolysis , Silica gel
