Title of article :
A Novel Synthesis of Aryl (alpha)-Imino Esters from Aryl Diazoacetate
Author/Authors :
Chen، Zhiyong نويسنده , , Huang، Haoxi نويسنده , , Wang، Yuanhua نويسنده , , Hu، Wen H. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Aryl (alpha)-imino esters were synthesized from the reaction of aryl diazoacetate with arylamine in the presence of diethyl azodicarboxylate (DEAD) catalyzed by dirhodium acetate. The (alpha)-imino esters were formed through fragmentation of corresponding aminals.
Keywords :
(alpha)-imino ester , dirhodium(II) acetate , (alpha)-diazoacetate , aminal , ammonium ylide