Title of article
Highly Efficient Binary and Remote Asymmetric Induction from a Single Allyltin Reagent with a Chiral Carbamate Moiety
Author/Authors
Nishigaichi، Yutaka نويسنده , , Takuwa، Akio نويسنده , , Ueda، Narifumi نويسنده , , Tamura، Ken-ichi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2518
From page
2519
To page
0
Abstract
Carbamate-protected chiral allyltin reagent was found to afford either syn- or anti-homoallyl alcohol via 1,4-remote asymmetric induction in the reaction with various aldehydes depending on the applied Lewis acid, TiCl4-THF or SnCl4, respectively. The both stereocontrols were so effective that the selectivities higher than 90% were realized in most cases.
Keywords
allylations , Lewis acids , protecting groups , Stereoselective synthesis , TIN
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110851
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