• Title of article

    Conversion of Nucleophilic Halides to Electrophilic Halides: Efficient and Selective Halogenation of Azinones, Amides, and Carbonyl Compounds Using Metal Halide/Lead Tetraacetate

  • Author/Authors

    Kim، Jeum-Jong نويسنده , , Kweon، Deok-Heon نويسنده , , Cho، Su-Dong نويسنده , , Kim، Ho-Kyun نويسنده , , Lee، Sang-Gyeong نويسنده , , Yoon، Yong-Jin نويسنده ,

  • Pages
    -193
  • From page
    194
  • To page
    0
  • Abstract
    AlCl3/Pb(OAc)4 and ZnBr2/Pb(OAc)4 are efficient electrophilic N- and (alpha)-C-halogenating agents. A variety of azinones, amides and carbonyl compounds were chemoselectively and regio­selectively N-, or (alpha)-C-halogenated in good to excellent yield using AlCl3/Pb(OAc)4 and ZnBr2/Pb(OAc)4 in acetonitrile.
  • Keywords
    (alpha)-C-halogenation , selective halogenation , metal halide/lead tetraacetate , N-halogenation , electrophilic halogenation
  • Journal title
    Astroparticle Physics
  • Record number

    110959