Mass transfer coefficient determination method for high-recovery pressure-driven membrane modules Original Research Article

A mass transfer coefficient determination method, based on the velocity variation method, is developed for pressure-driven membrane modules with large membrane area and high recovery rates. The method was used to measure mass transfer coefficients in the nanofiltration spiral-wound module Filmtec NF200-2540 (DOW-USA), with a membrane area of 2.6 m2, using two aqueous solutions of glycerol and xylose at 25ºC with a concentration of ca. 2 kg/m3. The permeate concentration was measured for circulation Reynolds numbers in the range 70–270 (based on the channel height and on the average feed velocity) and for a permeate flux of 69.2 l/m2h. The water recovery rate varied between 15% and 48% in the experiments. The intrinsic rejection coefficients of the membrane were determined for the two solutes by the developed extrapolation procedure to infinite Reynolds number. Based on these values and on the experimental data, the mass transfer coefficients were determined for the two solutes (950 < Sc < 1170) and for the different Reynolds number tested (70 < Re < 270) and the mass transfer correlation Sh = 0.33 Re0.5 Sc0.33 was obtained for this system.