Title of article
Synthesis of Precursors of gem-Difluorodiols and Amino Alcohols Using Electrochemical and Photochemical Reactions
Author/Authors
Fuchigami، Toshio نويسنده , , Murakami، Satoru نويسنده ,
Pages
-1014
From page
1015
To page
0
Abstract
Photo-initiated S-CF2 bond cleavage of electrochemically prepared 4-[difluoro(phenylthio)methyl]-1,3-dioxolanone and 4-[difluoro(phenylthio)methyl]-1,3-oxazolidinone in the presence of olefins provided the corresponding radical addition products, while the photolysis in the presence of aromatics and heteroaromatics provided radical substitution products in moderate yields.
Keywords
difluoromethyl radical , sulfide , radical addition , radical aromatic substitution , photoreaction
Journal title
Astroparticle Physics
Record number
111005
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