Title of article
Tri-tert-butylphosphine is an Efficient Promoter for the Trifluoromethylation Reactions of Aldehydes, Ketones, Imides and Imines
Author/Authors
Shibata، Norio نويسنده , , Nakamura، Shuichi نويسنده , , Toru، Takeshi نويسنده , , Mizuta، Satoshi نويسنده , , Sato، Takayuki نويسنده , , Fujimoto، Hiroyuki نويسنده ,
Pages
-266
From page
267
To page
0
Abstract
A truly catalytic nucleophilic trifluoromethylation reaction of carbonyl compounds with Ruppertʹs reagent, Me3SiCF3, has been shown to be efficiently promoted by a P(t-Bu)3-DMF system. Imines were also converted to the desired (alpha)-trifluoromethyl amines under similar reaction conditions.
Keywords
trifluoromethylation , Fluorine , Lewis bases , Imines , Aldehydes
Journal title
Astroparticle Physics
Record number
111010
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