Title of article :
Development of a Hemilabile P-P=O Ligand Based on the Concept of Conformational Control
Author/Authors :
Kondo، Kazuhiro نويسنده , , Suzuki، Kiyoto نويسنده , , Ishii، Satoru نويسنده , , Aoyama، Toyohiko نويسنده ,
Abstract :
Development of a new hemilabile P-P=O ligand based on the concept of conformational control is described. In Rh-catalyzed enantioselective phenylation of aromatic aldehydes with phenylboronic acid, MOD-DIOP monophosphine oxide is shown to function as a good ligand.
Keywords :
Boronic acid , hemilabile chiral ligands , asymmetric arylation , optically active diarylmethanol , rhodium catalysts
Journal title :
Astroparticle Physics
