Title of article
Metal-Halogen Exchange Using tri-n-Butyl Lithium Magnesate in the Diazine Series: Diazine 49
Author/Authors
Marsais، Francis نويسنده , , Buron، Frederic نويسنده , , Ple، Nelly نويسنده , , Turck، Alain نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
-1585
From page
1586
To page
0
Abstract
We report herein the ‘metal-halogen exchange’ reaction in the diazine series with lithium tri-n-tributylmagnesate. The reaction was performed with 2-iodopyrazine, 2-methylsulfanyl-4-iodopyrimidine and 3-iodo-6-phenylpyridazine. Benzophenone, aldehydes and diphenylsulfur were used as electrophiles affording alcohols and phenylsulfanyl derivatives with satisfactory to good yields.
Keywords
ate complex , magnesium , diazines , lithium , iodine
Journal title
Synlett
Serial Year
2006
Journal title
Synlett
Record number
111200
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