Author/Authors :
G. A. Kourouklis and B. Sundqvist ، نويسنده , , U. Edlund، نويسنده , , P. Jacobsson، نويسنده , , D. Johnels، نويسنده , , P. J. Jun، نويسنده , , P. Launois، نويسنده , , R. Moret، نويسنده , , P-A. Persson، نويسنده , , A. Soldatov، نويسنده , , T. W?gberg، نويسنده ,
Abstract :
We discuss the structural and dynamic properties of C60 polymerized under low-P, low-T conditions, and suggest that the disordered mixed orthorhombic-tetragonal-rhombohedral phases produced under these conditions arise from nucleation of molecular chains in random directions because of the quasi-free molecular rotation under standard reaction conditions in the fcc phase of C60. Polymerization in He gives results qualitatively different from those obtained in other media.
Keywords :
D. Phase transitions , D. Crystal structure , A. Fullerene , B. high pressure