Author/Authors :
Igor V. Magedov، نويسنده , , Lilia V. Frolova، نويسنده , , Mekan Ovezmyradov، نويسنده , , Donald Bethke، نويسنده , , Eric A. Shaner، نويسنده , , Nikolai G. Kalugin، نويسنده ,
Abstract :
The benzyne functionalization of chemical vapor deposition grown large area graphene and graphite was performed using a mixture of o-trimethylsilylphenyl triflate and cesium fluoride that react with the carbon surface. The reaction requires at least 2 days of treatment before the appearance of Raman and energy-dispersive X-ray spectral signatures that verify modification. Raman spectra of modified graphene and graphite show a rich structure of lines corresponding to Cdouble bond; length as m-dashCsingle bondC, Csingle bondH, and low frequency modes of surface-attached benzyne rings.
