Superplasticity in alumina enhanced by co-dispersion of 10% zirconia and 10% spinel particles Original Research Article

Superplastic deformation behavior is examined for Al2O3-based ceramics dispersed with 10 vol% ZrO2 and 10 vol% spinel (MgO·1.3 Al2O3) particles. The multiple-phase dispersion considerably decreases the rate of grain growth during deformation, leading to enhanced superplasticity (larger tensile elongation and higher strain rate). Maximum tensile elongation reaches 850% at a strain rate of 5.0×10−4 s−1 and at 1500°C. Grain growth during deformation is found to follow a theoretical model based on a grain boundary diffusion mechanism. The creep parameters corrected for concurrent grain growth are 2.2 as the stress exponent, 3.2 as the grain size exponent and 751 kJ/mol as the activation energy. Spherical ZrO2 particles embedded in elongated Al2O3 grains in deformed specimens suggest that the deformation mechanism of the present material is strongly related to grain boundary diffusion. Being different from other superplastic aluminas, cavities in the present material tended to grow in the direction parallel to the stress axis.