Title of article :
XPS study on the surface films of a newly designed Ni-free Ti-based bulk metallic glass Original Research Article
Author/Authors :
C.L. Qin، نويسنده , , J.J. Oak، نويسنده , , N. Ohtsu، نويسنده , ,
K. Asami، نويسنده , , A. Inoue، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2007
Abstract :
The electrochemical and corrosion behavior of a newly designed Ni-free Ti-based bulk metallic glass (BMG) was investigated. The Ti45Zr10Pd10Cu31Sn4 BMG exhibits excellent corrosion resistance after immersion in 3 mass% NaCl, 1 N H2SO4 and 1 N H2SO4 + 0.01 N NaCl solutions. X-ray photoelectron spectroscopy measurements were used to analyze the changes of the elements on the alloy surface before and after immersion in various solutions. The formation of Ti- and Zr-enriched highly protective thin surface films is responsible for the high corrosion resistance of this alloy in corrosive solutions.
Keywords :
Protective surface film , XPS measurements , Ni-free Ti-based BMG , Corrosion resistance
Journal title :
ACTA Materialia
Journal title :
ACTA Materialia