Title of article :
Effects of annealing atmosphere on the structural and electrical properties of (Na0.5K0.5)NbO3 thin films grown by RF magnetron sputtering Original Research Article
Author/Authors :
Bo-Yun Kim، نويسنده , , Tae-Geun Seong، نويسنده , , Gyu-Tae Seo، نويسنده , , Min-Soo Jang، نويسنده , , Sahn Nahm، نويسنده , , Jong-Yun Kang، نويسنده , , Seok Jin Yoon، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2012
Pages :
6
From page :
3107
To page :
3112
Abstract :
Amorphous (Na0.5K0.5)NbO3 (NKN) thin films were grown at 300 °C and subsequently annealed at 800 °C under Na2O, K2O and NKN atmospheres. When the annealing time was less than 50 min, K6Nb10.88O30 and Na2Nb4O11 secondary phases were formed in all the films. Moreover, they were also found in films annealed at 750 °C for 180 min under NKN atmosphere, indicating that they were transient phases formed when the sintering time and temperature were not sufficient. For the film annealed for 50 min under Na2O atmosphere, an Na-excess (Na1−xKx)NbO3 (N1−xKxN) phase was formed, whereas a K-excess N1−xKxN phase was developed in the film annealed under K2O atmosphere. On the other hand, a homogeneous NKN phase was developed in the film annealed under NKN atmosphere and this was maintained after a long period (100 min) of annealing at 800 °C. A high leakage current density and a small dielectric constant (εr) were observed for films annealed under Na2O and K2O atmospheres due to the evaporation of K2O and Na2O, respectively. Moreover, they exhibited a small remnant polarization (Pr) and a small coercive electric field (Ec). On the other hand, the film annealed under NKN atmosphere exhibited a very low leakage current density of 2.6 × 10−9 A cm−2 at 0.2 MV cm−1 and had good ferroelectric and piezoelectric properties of εr = 620, Pr = 11.7 μC cm−2, Ec = 133.8 kV cm−1 and d33 = 74 pm V−2 at 50 kV cm−1.
Keywords :
NKN thin film , Piezoelectricity , Sputtering , Annealing , Lead-free
Journal title :
ACTA Materialia
Serial Year :
2012
Journal title :
ACTA Materialia
Record number :
1146305
Link To Document :
بازگشت