Title of article
Activation of cis-ReOBr3(PPh3)2 by means of photoimmobilization Original Research Article
Author/Authors
L.V. Bogutskaya، نويسنده , , T.A. Palchevskaya، نويسنده , , L.A. Zyuzya، نويسنده , , V.M. Belousov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1995
Pages
7
From page
309
To page
315
Abstract
The possibility to activate cis-ReOBr3(PPh3)2 (inactive under homogeneous catalysis conditions) by photoimmobilization on different supports is demonstrated. The systems obtained are active in the liquid-phase hydrogenation of 1-hexene and m-nitrobenzoic acid. We propose various mechanisms for grafting the complex in darkness and under UV irradiation. The samples photoimmobilized on anatase are the most active.
Keywords
Photoimmobilization , Hydrogenation , Rhenium complex , Activation
Journal title
Applied Catalysis A:General
Serial Year
1995
Journal title
Applied Catalysis A:General
Record number
1148190
Link To Document