Title of article
Oxidation of sulfoxides to sulfones by hydrogen peroxide over Ti-containing zeolites Original Research Article
Author/Authors
Patrice Moreau، نويسنده , , Vasile Hulea، نويسنده , , Sylvie Gomez، نويسنده , , Daniel Brunel، نويسنده , , Francesco Di Renzo and Corine Gérardin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1997
Pages
11
From page
253
To page
263
Abstract
The oxidation reaction of dibutylsulfoxide to the corresponding sulfone by dilute hydrogen peroxide is investigated over Ti-containing zeolites as catalysts; Ti-beta is more active than TS-1, as for the oxidation of sulfides under similar conditions. The kinetic parameters are determined over Ti-beta in t-butanol as solvent, and the kinetic law of the sulfoxide oxidation reaction is established. The influence of the reaction temperature and effect of the solvent are also reported.
Keywords
Dibutylsulfone , Hydrogen peroxide , Titanosilicates , Dibutylsulfoxide , Oxidation
Journal title
Applied Catalysis A:General
Serial Year
1997
Journal title
Applied Catalysis A:General
Record number
1148896
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