Partial oxidation of methane to synthesis gas over iridium–nickel bimetallic catalysts Original Research Article

Partial oxidation of methane to synthesis gas was carried out using supported iridium–nickel bimetallic catalysts, in order to reduce loading levels of iridium and nickel, and to avoid carbon deposition on nickel-based catalysts by adding iridium. The performance of supported iridium–nickel bimetallic catalysts in synthesis gas formation depended strongly upon the support materials. La2O3 gave the best performance among the support materials tested. Ir(0.25 wt%)–Ni(0.5 wt%)/La2O3 afforded 36% conversion of methane (CH4/O2=5) to give CO and H2 with the selectivities of above 90% at 800°C, and those at 600°C were 25.3% conversion of methane and CO and H2 selectivities of about 80%, respectively. Reduced monometallic Ir(0.25 wt%)/La2O3 and Ni(0.5 wt%)/La2O3 catalysts did not produce synthesis gas at 600°C. A higher conversion of methane was obtained by synergistic effects. The product concentrations of CO, H2, and CO2, and CH4 conversion were maintained in high values, even increasing the space velocity of feed gas over Ir–Ni/La2O3 catalyst, indicating that rapid reaction takes place. As a by-product, a small amount of carbon deposition was observed, but carbon formation decreased with increasing the space velocity. On the other hand, with reduced monometallic Ni(10 wt%)/La2O3 catalyst, yield of synthesis gas and carbon decreased with increasing the space velocity.