Activity enhancement of mixed lanthanum-copper-iron-perovskites in the CO+NO reaction Original Research Article

The objective of this work was to prepare La2Cu1−xFexO4 substituted perovskites and to measure their catalytic activity in the CO+NO reaction. Although no real mixed oxide structure was formed, a synergetic effect was observed between copper and iron. The catalytic activity increased by a factor of 3 when the iron content reached 30%, i.e. for the LaCu0.7+LaFe0.3 ternary system. This activity enhancement has been attributed to an increase in the surface concentration of metallic copper which is formed under reaction conditions and can be considered as the main active species in the CO+NO reaction. To improve the activity, La, Cu and/or Fe oxides were prepared onto a MgAl2O4 spinel support in order to increase the number of surface copper sites. A reaction of the MgAl2O4 support with lanthanum to form LaAlO3 was observed. No Cu/Fe synergetic effect was obtained for LaCu0.7+LaFe0.3/MgAl2O4, the most active catalyst being the system La2Cu /MgAl2O4. It seems that for the latter, the support’s effect on the dispersion of copper was the most pronounced.