Title of article :
Pd–heteropoly acid as a bifunctional heterogeneous catalyst for one-pot conversion of citronellal to menthol Original Research Article
Author/Authors :
Kelly A. da Silva Rocha، نويسنده , , Patricia A. Robles-Dutenhefner، نويسنده , , Edésia M.B. Sousa، نويسنده , , Elena F. Kozhevnikova، نويسنده , , Ivan V. Kozhevnikov، نويسنده , , Elena V. Gusevskaya، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
Pd–H3PW12O40/SiO2 catalyzes the one-pot transformation of (+)-citronellal to menthol via acid-catalyzed cyclization followed by Pd-catalyzed hydrogenation, with 92% yield of menthol at 100% citronellal conversion and 85% stereoselectivity for the desired (−)-menthol.
Keywords :
Menthol , Palladium , Heteropoly acid , Bifunctional catalysis , citronellal
Journal title :
Applied Catalysis A:General
Journal title :
Applied Catalysis A:General
