Title of article :
The effect of oxalic acid and glyoxal on the VO(acac)2-catalyzed cyclohexane oxidation with H2O2 Original Research Article
Author/Authors :
Alexander Pokutsa، نويسنده , , Yulia Kubaj، نويسنده , , Andriy Zaborovskyi، نويسنده , , Dariya Maksym، نويسنده , , Jacques Muzart، نويسنده , , Andrzej Sobkowiak، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
A new protocol for the effective oxidation of cyclohexane in acetonitrile at 40 °C and atmospheric pressure into cyclohexanol, cyclohexanone and cyclohexyl hydroperoxide using hydrogen peroxide as the oxidant, vanadyl(IV)-acetylacetonate as the catalyst, oxalic acid and glyoxal as additives is presented with some reaction mechanism proposals.
Keywords :
Vanadium(V)-oxide , Vanadyl(IV)-acetylacetonate , Oxalic acid , Hydrogen peroxide , Oxidation , Cyclohexane , Glyoxal
Journal title :
Applied Catalysis A:General
Journal title :
Applied Catalysis A:General