Steam resistant CoLa-mordenite catalysts for the SCR of NOx with CH4 Review Article

The stabilization of Co-mordenite catalysts through lanthanum exchange is reported here. The effect of exchange order and calcination conditions upon the reduction of NOx to N2 at 500 °C was tracked during 400 h on a stream containing NOx, CH4, O2 and 10% H2O. Both the fresh and used catalysts were characterized through TPR, Raman spectroscopy, FTIR spectroscopy using CO as probe molecule, and XPS. These techniques revealed that the CoLa-mordenite catalysts which were not affected by the severe hydrothermal treatment showed no sign of Co or La migration out of the exchange positions. Instead, those that rapidly deactivated showed the formation of cobalt oxides and, in some cases, the migration of the cations to other exchange positions. The presence of exchanged lanthanum seems to preserve the integrity of the zeolite structure preventing the migration of cobalt ions with the subsequent formation of cobalt oxides which favors the reaction of methane with O2, thus decreasing N2 production.