Title of article :
Tin exchanged zeolite as catalyst for direct synthesis of α-amino nitriles under solvent-free conditions Original Research Article
Author/Authors :
Arpan K. Shah، نويسنده , , Noor-ul H. Khan، نويسنده , , Govind Sethia، نويسنده , , S. Saravanan، نويسنده , , Rukhsana I. Kureshy، نويسنده , , Sayed H.R. Abdi، نويسنده , , Hari C. Bajaj، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
Sn exchanged HBeta zeolite was prepared and characterized by PXRD, surface area, TPD and TEM analysis. The Sn exchanged zeolite was found to be highly efficient catalyst for the direct synthesis of α-amino nitrile from various ketones and aldehydes with amine and trimethyl silylcyanide (TMSCN) under solvent-free condition. Excellent yield of α-amino nitrile (up to 96%) was achieved within 10–120 min at room temperature. The Sn exchanged HBeta zeolite was recovered and reused several times without the loss of its catalytic performance.
Keywords :
Heterogeneous catalysis , Zeolite , Strecker reaction , ?-amino nitriles
Journal title :
Applied Catalysis A:General
Journal title :
Applied Catalysis A:General