Title of article
Solvent free synthesis of coumarins using environment friendly solid acid catalysts Original Research Article
Author/Authors
Shrinivas Ghodke، نويسنده , , Heemanshu Patel and Uma Chudasama ، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
8
From page
219
To page
226
Abstract
Solid acid catalysts, ZrPW (Zirconium(IV) Phosphotungstate) and 12-TPA/ZrO2 [12-Tungstophosphoric acid (12-TPA) supported onto ZrO2] have been synthesized. The catalysts have been characterized for chemical stability, elemental analysis by ICP-AES, TGA, FTIR, SEM, EDX, XRD, surface area (BET) and surface acidity (NH3-TPD). The performance of these materials as solid acid catalysts has been explored by studying Pechmann condensation as a model reaction, wherein phenols have been treated with methyl acetoacetate to give coumarins, under solvent free conditions using conventional heating as well as microwave heating. Catalytic activity of both the solid acid catalysts have been compared and correlated with surface properties of the materials.
Keywords
Solid acid catalyst , Zirconium(IV) Phosphotungstate , Coumarin derivatives , 12-TPA supported solid acid catalyst , Pechmann condensation , Microwave-assisted synthesis
Journal title
Applied Catalysis A:General
Serial Year
2013
Journal title
Applied Catalysis A:General
Record number
1157285
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