Title of article
Thermal isomerization of cis-[Fe(cyclam)Cl2]Cl·H2O complex in the solid state
Author/Authors
Eduardo H.S. Sousa، نويسنده , , Cristiane P. Oliveira، نويسنده , , Luiz C.G. Vasconcellos، نويسنده , , Luiz G.F. Lopes، نويسنده , , Izaura C.N. Di?genes، نويسنده , , Idalina M.M. Carvalho، نويسنده , , José C.V. Miranda، نويسنده , , Francisco A. Dias Filho، نويسنده , , ?caro S. Moreira، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2001
Pages
5
From page
141
To page
145
Abstract
The solid state thermal isomerization of cis-[Fe(cyclam)Cl2]Cl·H2O (cyclam is 1,4,8,11-tetraazacyclotetradecane), is investigated by TG/DSC, electrochemical and vibrational spectroscopic methods. The thermal isomerization of this complex was found to be water dependent and endothermic. An aquation–anation pathway that precedes the macrocyclic ligand stereochemical rearrangement in the complex is proposed.
Keywords
Iron(III) complex , Solid state , Cyclam , Cis–trans isomer , Thermal isomerization
Journal title
Thermochimica Acta
Serial Year
2001
Journal title
Thermochimica Acta
Record number
1195182
Link To Document