Title of article :
Simple derivation of the frequency dependent complex heat capacity
Author/Authors :
J.-L. Garden، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2007
Abstract :
This paper gives a simple derivation of the well-known expression of the frequency dependent complex heat capacity in modulated temperature experiments. It aims at clarified again that the generalized calorimetric susceptibility is only due to the non-equilibrium behaviour occurring in the vicinity of thermodynamic equilibrium of slow internal degrees of freedom of a sample when the temperature oscillates at a well determined frequency.
Keywords :
Complex heat capacity , ac-Calorimetry , Internal degree of freedom , Relaxation time constants
Journal title :
Thermochimica Acta
Journal title :
Thermochimica Acta