Title of article :
Dielectric data, densities, refractive indices, and their deviations of the binary mixtures of N-methyldiethanolamine with sulfolane at temperatures 293.15–328.15 K and atmospheric pressure
Author/Authors :
Mehdi Vahidi، نويسنده , , Behnoosh Moshtari، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2013
Abstract :
Dielectric constants (ɛ), densities (ρ), and refractive indices (nD) were measured for binary blend of tetramethylensulfone (TMS) or sulfolane and N-methyldiethanolamine (MDEA) at temperatures ranging from 293.15 to 328.15 K and atmospheric pressure over the whole mole fraction range. From these experimental data, the excess molar volume (image), and deviations in refractive indices (ΔnD), and relative permittivities (Δɛ), were calculated. These quantities were fitted to the Redlich–Kister polynomial equation to derive the binary adjustable parameters and standard errors. The effective dipole moment of pure liquid was calculated by using of Kirkwood–Frohlich equation.
Keywords :
Dielectric constant , Refractive index , density , Sulfolane , N-Methyldietanolamine
Journal title :
Thermochimica Acta
Journal title :
Thermochimica Acta