Preparation of polymeric sheet porphyrin complexes and their environmentally benignly catalytic activity

The polymeric meso-tetra-(1,5-naphthalene bisulfonyloxo)phenylporphyrin and its complexes (PTNBSOPPM, M=Co, Mn, Fe) have been prepared in the presence of phase-transfer catalyst. Catalyzed by polymeric porphyrin complexes (PTNBSOPPM), styrene can be aerobic oxidized. The main products come from cleavage of double bond is in catalytic oxidation of styrene or α-methyl styrene.