Interaction between dispersed photochromic compound and polymer matrix

Thin films containing photochromatic spiropyran (SP) was prepared from polymethyl methacrylate (PMMA), polyethyl methacrylate (PEMA), poly(n-butyl methacrylate) (PnBMA), and styrene–butadiene–styrene copolymer (SBS). The thin films were illuminated with the ultraviolet light (365 nm) under various temperatures. The photochromic response was monitored with a multichannel photodetector. The results show that the photocoloring rate of SP was faster in PMMA, while the thermal decoloring rate was faster in SBS. In addition, the decoloring rate was higher in a polymer matrix with lower Tg.