Title of article
Controlled one-step synthesis of a diblock copolymer
Author/Authors
M. Nasser-Eddine، نويسنده , , C. Delaite، نويسنده , , G. Hurtrez، نويسنده , , P. Dumas، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
6
From page
313
To page
318
Abstract
Well-defined block copolymers were obtained from 4-hydroxy-butyl-2-bromoisobutyrate dual initiator, combining tert-butylmethacrylate ATRP and ε-caprolactone ROP in a one-step process. Using AlEt3 as coinitiator in a ROP catalytic process, the variation of the AlEt3/initiator ratio permits to modulate the ROP rate and so to control the final block copolymer composition. Nevertheless, slight interferences between the two polymerizations were observed.
Keywords
dual initiator , One-step polymerization , Coordinated anionic polymerization , block copolymers , atom transfer radical polymerization
Journal title
European Polymer Journal(EPJ)
Serial Year
2005
Journal title
European Polymer Journal(EPJ)
Record number
1212589
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