Title of article :
NUCLEOPHILIC REACTIVITY OF THE PEROXIDE ANION IN AQUEOUS–ALCOHOLIC SOLUTIONS IN THE PRESENCE OF DETERGENTS
Author/Authors :
Popov، A.F. نويسنده , , Vakhitova، L.N. نويسنده , , Skrypka، A.V. نويسنده , , Bogutskaya، K.V. نويسنده , , Taran، N.A. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
The reactivity of hydroxide and peroxide anions with 4-nitrophenyl N,N-dimethylcarbamate in aqueous–alcoholic detergent media and in “oil in water” microemulsions has been studied. Aqueous–alcoholic solutions of cationic (CTAB) and neutral (Triton X-100) surface active substances have promise for decomposition of substrates by a nucleophilic mechanism.
Keywords :
Hydrogen peroxide , nucleophilic substitution , surface active substances , Microemulsion
Journal title :
Theoretical and Experimental Chemistry
Journal title :
Theoretical and Experimental Chemistry