Title of article :
REACTIVITY OF CYANO-SUBSTITUTED FLUORENES IN REACTION WITH THE TEMPO RADICAL
Author/Authors :
Opeida، I.A. نويسنده , , Matvienko، A.G. نويسنده , , Bakurova، O.Z. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The rate constants for the reaction of the TEMPO radical with fluorene, 2-cyanofluorene, and 9-cyanofluorene were determined by ESR. A comparison was made of the reactivity of the hydrocarbons in reaction with the TEMPO radical and the peroxyl radical. The quantum-chemical characteristics of the radicals and particles taking part in the reactions and also the characteristics of the transition states in the reactions of the TEMPO radical and cumenylperoxyl radical with fluorene were obtained by the PM3 method.
Keywords :
TEMPO radical , Kinetics , chemical bond dissociation energy , ionization potential , ESR , electron affinity , transition state , alkylarenes , rate constants of hydrogen atom abstraction
Journal title :
Theoretical and Experimental Chemistry
Journal title :
Theoretical and Experimental Chemistry
