Title of article :
SUBSTRATE SELECTIVITY AND MECHANISM OF OXIDATION OF ALKANES BY PEROXYNITROUS ACID IN AQUEOUS SOLUTION
Author/Authors :
Popov، V. G. نويسنده , , Lobachev، V.L. نويسنده , , Matvienko، Ya.V. نويسنده , , Rudakov، E.S. نويسنده , , Tret’yakov، V.P. نويسنده , , Min’ko، L.A. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Abstract :
The relative rate constants (krel) were measured for the oxidation of alkanes (RH) by peroxynitrous acid (HOONO) in aqueous solutions at 25 °C. The krel values for the reactions of RH with HOONO and with OH radicals in the series of C2-C7 alkanes and the isotopic effects (c-C6H12/c-C6D12) agree. However, the krel value for methane was lower than for its reaction with OH. Possible reaction mechanisms are discussed.
Keywords :
Kinetics , Mechanism , reactions in solution and gas phase , Peroxynitrous acid , alkanes , Oxidation
Journal title :
Theoretical and Experimental Chemistry
Journal title :
Theoretical and Experimental Chemistry
