Title of article :
NATURE OF INITIATORS FOR INDIRECT ELECTROCHEMICAL REDUCTIVE DEGRADATION OF POLYCARBONATES IN DIMETHYLFORMAMIDE
Author/Authors :
Rogalskii، S.P. نويسنده , , Pud، A.A. نويسنده , , Shapoval، G.S. نويسنده , , Melnik، A.L. نويسنده , , Bryk، M.T. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
We have established the nature of the species initiating indirect electrochemical reductive degradation of polycarbonates in dimethylformamide solutions. Such compounds include two types of nucleophiles: hydroxide ions, and also their complexes with dimethylformamide. We have shown that it is possible to use indirect electrochemical reductive degradation for surface and bulk modification of polycarbonates.
Keywords :
electrolysis , dimethylformamide , Charge transfer complex , nucleophiles , Homogeneous catalysis , polycarbonate
Journal title :
Theoretical and Experimental Chemistry
Journal title :
Theoretical and Experimental Chemistry