Synthesis and catalytic properties of TS-1 with mesoporous/microporous hierarchical structures obtained in the presence of amphiphilic organosilanes

Titanosilicates TS-1 with mesoporous/microporous hierarchical structures have been synthesized in the presence of an organosilane surfactant. Highly porous crystals, with regular pores of ca. 2.5–3.5 nm diameter, are obtained under hydrothermal conditions similar to those used for the preparation of conventional catalysts. The organosilane has a great influence on the textural properties of TS-1, but does not significantly affect the amount and coordination of Ti species in the framework. Mesoporous TS-1 have been used as catalysts in various oxidation reactions with an aqueous H2O2 and their activity has been compared with those of a conventional TS-1 and a mesoporous amorphous TiMCM-41. Data show that mesoporous TS-1 does not possess the expected properties for hierarchical catalysts, i.e. the properties of the conventional catalysts with advantages of mesoporous solids. In particular, the gain in diffusion due to intracrystalline mesopores is totally inhibited by the increase of the hydrophilic character of the zeolite, resulting from very high silanol group populations on the external surface.